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![]() This area is crucial for free throws and certain violations.
![]() ![]() It has a high charge density and will have a marked distorting effect on any negative ions which happen to be near it.Ī bigger 2+ ion has the same charge spread over a larger volume of space. Exactly the same arguments apply to the nitrates.Įxplaining the trend in terms of the polarising ability of the positive ionĪ small 2+ ion has a lot of charge packed into a small volume of space. Note: If you are working towards a UK-based exam (A level or its equivalent) and haven't got copies of your syllabus and past papers follow this link to find out how to get hold of them.ĭetailed explanations are given for the carbonates because the diagrams are easier to draw, and their equations are also easier. You should look at your syllabus, and past exam papers - together with their mark schemes You need to find out which of these your examiners are likely to expect from you so that you don't get involved in more difficult things than you actually need. This page offers two different ways of looking at the problem. The ones lower down have to be heated more strongly than those at the top before they will decompose. The nitrates also become more stable to heat as you go down the Group.īoth carbonates and nitrates become more thermally stable as you go down the Group. Magnesium and calcium nitrates normally have water of crystallisation, and the solid may dissolve in its own water of crystallisation to make a colourless solution before it starts to decompose.Īgain, if "X" represents any one of the elements:Īs you go down the Group, the nitrates also have to be heated more strongly before they will decompose. ![]() Brown nitrogen dioxide gas is given off together with oxygen. The nitrates are white solids, and the oxides produced are also white solids. The effect of heat on the Group 2 nitratesĪll the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. The carbonates become more stable to heat as you go down the Group. If "X" represents any one of the elements:Īs you go down the Group, the carbonates have to be heated more strongly before they will decompose. Thermal decomposition is the term given to splitting up a compound by heating it.Īll of these carbonates are white solids, and the oxides that are produced are also white solids. The effect of heat on the Group 2 carbonatesĪll the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. It describes and explains how the thermal stability of the compounds changes as you go down the Group. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. THERMAL STABILITY OF THE GROUP 2 CARBONATES AND NITRATES Replacing r 0 as before yields the full Kapustinskii equation.Thermal decomposition of the Group 2 carbonates and nitrates The derivation of the later form of the Kapustinskii equation followed similar logic, starting from the quantum chemical treatment in which the final term is 1 − d / r 0 where d is as defined above. Finally, Kapustinskii noted that the Madelung constant, M, was approximately 0.88 times the number of ions in the empirical formula. In addition, the Born exponent, n, was assumed to have a mean value of 9. Kapustinskii replaced r 0, the measured distance between ions, with the sum of the corresponding ionic radii. It is named after Anatoli Fedorovich Kapustinskii who published the formula in 1956. The Kapustinskii equation calculates the lattice energy U L for an ionic crystal, which is experimentally difficult to determine. ![]() ![]() ![]() Reference Page By Page Labels: Enter “l:" keyword followed by a page label to specify page numbers indirectly via page labels.įor example, the following instruction will delete pages in PDF document with the page labels "i" and "14": "l:i,l:14". Reference Pages By Destination: Enter “d:" keyword followed by a destination name to refer to the corresponding page.įor example, the following keywords will delete 2 pages in PDF document, pointed by named destinations "Client ID: 25896325"Īnd "Client ID: 46985645": d:Client ID: 25896325,d:Client ID: 46985645. Where bookmarks "John Doe" and "Paul Davis" pointing to: b:John Doe,b:Paul Davis. For example, the following instruction will delete pages in PDF document, Specify page numbers indirectly via bookmarks. Reference Pages By Bookmarks: Enter “b:" keyword followed by a bookmark name that goes to the page to The order of the pages in the list of page ranges is not important. This will delete pages 1,3,10,11,12,13,14 from the PDF document. Single pages and multiple page ranges can be specified. Absolute Page Referencing: Enter a list of absolute page numbers for deleting Page numbers or indirectly via bookmarks, named destinations or page labels. ![]() Pages can be specified either directly as absolute Step 3 - Specify Pages to Delete Enter a list of pages and page ranges that needs to be deleted. Step 2 - Open “Delete Pages” Dialog Select “Plug-ins > Split Documents > Delete Page Ranges…” from the main Acrobat® menu. Deleting Page Ranges Step 1 - Open a PDF File Start Adobe® Acrobat® application and open a PDF file using “File > Open…” menu. The batch processing functionlaity requires Acrobat Pro. You can download trial versions of both Adobe Acrobat and AutoSplit™. What do I need? You need a copy of Adobe Acrobat Standard or Professional along with AutoSplit™ plug-in installed on your computer in order to use this tutorial. The second part explains how to define your own PDF processing "action" that executes "Delete Page Ranges" batch command using Action Wizard tool in Adobe Acrobat Pro. The first part explains how to delete pages by specifying pages both directly and indirectly. The instructions below consist of two parts. This operation is also available in Action Wizard (Acrobat's batch processing tool) and can be used for automating of document processing workflows. Indirect page referencing provides a very flexible way to specify page ranges. Pages can be specified either directly as absolute page numbers or indirectly via bookmarks, named destinations or page labels. Deleting Page Ranges Using AutoSplit™ Plug-in For Adobe® Acrobat® What is it for? The AutoSplit™ plug-in offers a powerful way for deleting pages from PDF documents by specifying a list of individual pages and page ranges. ![]() ![]() The heaviest configuration (never built) would have been able to launch 200 tons into orbit. Other payloads than Buran, with mass as high as 80 metric tons, could be lifted to space by Energia, as was the case on its first launch. The Energia was designed from the start to be configured for a variety of uses, rather than just a shuttle launcher.The Space Shuttle's boosters used solid propellant. The Buran’s boosters used liquid propellant (kerosene/oxygen).There were some plans for constructing a fully reusable Energia carrier, called Uragan (Russian for Hurricane). Both designs featured reusable boosters (although reusability was not demonstrated on Energia). Space Shuttle which had reusable main engines in the orbiter. The main engines of the Buran were mounted on the core Energia stage and thus destroyed when it burns up in the atmosphere, unlike the U.S.In contrast, in the American Space Shuttle system, the three main engines on the rear of the orbiter comprised the second stage launch propulsion system, and the External Tank and twin boosters were not used to launch anything except an orbiter. The orbiter had no main rocket engines, freeing space and weight for additional payload the largest cylindrical structure is the Energia carrier-rocket, not just a fuel tank. Buran was not an integral part of the system, but rather a payload for the Energia launcher.The ODU maneuvering system on the Buran is very similar to the OMS/RCS systems of the Space Shuttle. It also appears that the Buran has some of the spherical shaped tanks for storing the fluids and gasses the shuttle needs to operate. The Buran has Electronic equipment sitting on shelves in nearly the same locations as where the avionics bays would be in the Space Shuttle. All of the crew hatches and thruways are in the exact same places. The section view of the Buran with the outer skin removed shows the Buran as having the same crew compartment layout as the Space Shuttle. The Buran-Energia launch stack is a very close match to the Space Shuttle stack but the Buran used different fuel and a different type of engine. There are far more similarities between the two orbiters besides the fact that they are relatively the same size and shape. Here is an outline of the similarities and differences between both programs and their vehicles. ![]() Most people are aware of the American Space Shuttle program than the Russian Buran Program. In 2002, the Buran was destroyed when the hangar in which it was stored, located at the Baikonur cosmodrome, collapsed. There were four other Buran shuttles named OK-1K2 Ptichka, OK-2K1 Baikal, Shuttle 2.02 and Shuttle 2.03 some of which flew only test flights and were incomplete. The Buran spacecraft was the only Soviet space vehicle to launch into space before the program closure. The Buran (Russian for Snowstorm or Blizzard) was the name of both a Soviet reusable spacecraft and the name of the Soviet reusable space vehicle program. The main intention of this blog post is to introduce collectors to the world of spacecraft and vehicles by starting off with a post about a Soviet Reusable spacecraft similar to the American Space Shuttle Orbiter. However, some people own models of spacecraft mounted on top of aircraft such as the Boeing 747 or An-225. Not many people on MAC are interested in collecting models of space vehicles. ![]() ![]() For the sake of simplicity, all data is presented in percentage without explicitly showing "%". If any applicable buildings were found, roll 30% chance of debuff, 70% chance of buff.Īll calculations will assume that at least 100,000 cookies have been baked, at least one building's number is more or equal to 10, the Dragonflight effect is not active, and Sugar Lumps are growing.5% chance to add Dragon Harvest and/or Dragonflight to the pool, if their auras are selected.25% chance to add Building Special, if you own more than or equal to 10 total buildings.10% chance to add Cursed Finger to the pool.If the Dragonflight effect is active, re-roll with 5% chance to add Click Frenzy (total chance: 0.5%).If previous step fails (70%), 3% chance to add Chain and Storm to the pool (2.1% total), if at least 100,000 cookies have been baked this game.Cookie Clicker Wiki is a FANDOM Games Community. 30% chance to add Elder Frenzy, Chain and Storm to the pool. If you look in your stats menu, it should say (Golden cookie clicks) Cookies per click : 1 Cookie clicks : Hand-Made cookies : 1000000000 Golden Cookie Clicks : (edited by A Fandom user) 0.If Skruuia, Spirit of Scorn is currently selected in the Pantheon: Add Clot, Ruin, Clot and Ruin to the pool (3 total each).If Building Special, check for buildings with 10 or more built, then pick one.80% chance to remove the previous outcome from the pool, if there is at least one in the pool.With the Dragonflight aura, Reality Bending has no effect on the chance of Dragonflight. With Reaper of Fields, Reality Bending has no effect on the chance of Dragon Harvest.If either roll succeeds, Dragon Harvest is added with 100% chance if Reaper of Fields is active, or 10% if Reality Bending is active, and Dragonflight is added with 100% chance if the aura Dragonflight is active, or 10% if Reality Bending is active.Make two rolls with 15% and 5% chance of success, respectively (total chance: 19.25%).To unlock Krumblor, the player must purchase the Heavenly Upgrade. Switching auras costs one of the highest tier building owned. An aura can be selected by clicking on the dragon. By sacrificing cookies and buildings to Krumblor, the player will unlock selectable auras which provide various benefits in the game. If any of the auras Reaper of Fields, Dragonflight, or Reality Bending is active, Dragon Harvest and/or Dragonflight may be added. Krumblor the cookie dragon is a widget that was added in v1.9 of Cookie Clicker.0.05% to add Sweet, if Sugar Lumps are growing.25% chance to add Building Special to the pool, if you own more than or equal to 10 total buildings.If roll succeeds and the Dragonflight effect is active, re-roll with 5% chance to add Click Frenzy (total chance: 0.5%).10% chance to add Click Frenzy to the pool. ![]() ![]() 5% chance to add Everything Must Go to the pool, if current season is Business Day.Golden cookies, small cookies that appear in random locations and. 3% chance to add Chain and Storm to the pool, if at least 100,000 cookies have been baked this game. The player may also purchase upgrades to increase cookie production for these buildings.For Golden cookies, the process is as follows: ![]() ![]() In IT, BPA is routinely applied to automate nighttime data center operations and the human staff receives alerts only in case of an emergency. Back-office operationsīusiness process automation optimizes some of the core processes that happen beyond the customer desk, such as synchronizing sales and warehouse databases, keeping billing and financial records, logistics, delivery and product dispatch. You can use business process automation to search for healthcare, legal and criminal records as well as for marketing, customer support and scientific research. Researchīusinesses can use automated tools to research their databases and to derive insights from different types of data. In mining industry, for instance, the use of robots and unmanned vehicles is becoming omnipresent. If the task in question requires manual operations that can potentially put humans at risk, then it is fit for automation. When to apply business process automation? Which business processes should you streamline and which should you leave intact? Let us discuss how businesses estimate if a particular process is fit for automation. By demonstrating dedication to creating a better customer experience, you will ultimately increase customer loyalty. Meeting customer expectationsĪdhering to high standards helps you ensure customer satisfaction. ![]() BPA provides a record for the steps of each process and helps you prove compliance should any disputes arise during audits. Setting higher business standards and adhering to them is one of the advantages of business process automation. Further, business process automation helps accelerate operations and increases time-to-value. Once you have the workflows for each process carefully mapped out, it is easy to eliminate redundant and ineffective steps. You will have to perform process mapping before you proceed with business process automation and it has several important benefits. First, it enables you to get more clarity on how your business processes actually take place. This gives your staff guidelines on how each process should be executed, helps set quality criteria and finally raises performance standards. By automating a few processes, your organization will gradually adopt a culture of continuous transformation, innovative technology and better organization standards on a large scale. Most companies find the digital transformation goal unapproachable and overwhelming to handle at once. O nly 44% of enterprises are ready for digital disruption. If you’re still unsure of the countless benefits of business process automation, below are a few examples that you may find interesting and beneficial. ![]() The potential benefits of BPA are compelling in the digital age and that explains why it is now poised for wider use within enterprises. BPA lays the foundation of a robust customer experience and relation strategy. Then there are also hard to quantify yet handsome payoffs. There are many sound reasons why BPA is steadily making its way into the enterprise environment.īPA capabilities enable you to identify problems and opportunities much earlier because you have complete visibility within your workflow mechanism. They are turning to BPA to streamline operations, eliminate manual errors, optimize cost, attain agility and augment the overall digital capabilities. ![]() Most enterprises, if not all, are supercharging their digital transformation efforts by injecting a heavy dose of BPA (Business Process Automation) use cases into their enterprise environment. ![]() ![]() ![]() ![]() We'll keep this list updated as new options become available. And you don't have to look far for some discounts - we've rounded up the best dash cam deals happening now and posted them below. Thinkware U1000: Best for driver assistance. It costs around 320 to purchase the front, in-cabin, and rear cameras. best affordable dash cam: Whats the best dash cam under 100 1. With more advanced features come higher prices, though, so it's important to spend sufficient time searching for dash cam deals that can help you save a few bucks. We also like Rexing's new V5 dash cam, which includes an in-cabin camera, voice control, and 4K resolution. So, if youre looking for an affordable, reliable, and feature-packed dash cam that caters. And it will still only cost you a fraction of what you may end up saving in insurance and repair costs.įar from being gimmicky devices, the best dash cameras offer an array of smart functions that make them nearly essential these days. In fact, the T130 is the 1 recommended 3-channel dash cam on Reddit. There are a vast amount of dash cams out there, so whether you're looking for a budget-friendly option or want to grab a more expensive model with extra features, you can find something that should work for you and your budget. One of the most important roles dash cameras play is that you can use the videos you record as vital evidence in the event of a collision. You can spend 50 bucks on a bare-bones, off-brand model, or you can pony up several hundred for a fully featured bundle. By mounting one of these compact cameras in your vehicle, you'll be able to record footage while you're driving - and that can be helpful for a lot of reasons. Naturally, price points are all over the map, too. To start with, the dash cam features a 3 inches LED touchscreen display that shows off your current location, route, speed, and much more using the built-in GPS technology. The popularity of dash cams has been growing over the past decade, especially with so many good quality budget dash cams becoming available. It has every feature you can think of and more. On the other hand, the KDLINKS model has an even higher resolution of 2.7k, 360-degree camera angle and all of the equipment included in the package. One of the most expensive options on our list is the Nextbase 622GW. The first one is great because it has 2 K resolution, sleek design and all of the advanced dash cam features. Investing in a dash cam is a good idea for just about anyone. They are the Rexing V1 model and the KDLINKS X3 model. ![]() ![]() ![]() This adhesive-backed foam strip seals any remaining gap between the fan shroud and radiator so that the fans are only moving air that has passed through the radiator core as opposed to pulling in air from the engine bay, resulting in improved cooling efficiency. The fan shroud serves another very important purpose: It secures the fan blades, preventing potential damage to other essential engine components.Īll Mishimoto aluminum fan shrouds include an adhesive protective strip. Classic Industries offers a wide selection of Cooling System Components for your Dodge Neon. Works as expected, now the engine stays cool. Is your radiator fan harness missing, or damaged No problem, we offer a replacement harness now that uses the factory plugs. A Mishimoto fan shroud will notably improve engine cooling performance by delivering more air to the SRT4 radiator and driving out excess heat. I need the max cooling fan shroud for an 87, its probably the same part number. Overall a perfect match except I had to replace the captive nut that the fan shroud attaches to as the new one was for an M6 fastener. Dodge Neon 2.4L 2003, Electric Fan with Aluminum Shroud Kit by Mishimoto®. The longevity of your engine depends on keeping your engine running cool, especially during those unbearably hot days. All Mishimoto fan shrouds are significantly lighter than standard fan shrouds. The Mishimoto Dodge Neon SRT-4 aluminum fan shroud kit will considerably improve engine cooling functions and the overall performance of your vehicle. ![]() ![]() ![]() Shatalebi M-A, Safaeian L, Baradaran A, Alamdarian M. Evidence-Based Complementary and Alternative Medicine. Evaluation of beeswax influence on physical properties of lipstick using instrumental and sensory methods. Kasparaviciene G, Savickas A, Kalveniene Z, Velziene S, Kubiliene L, Bernatoniene J. Asian Pacific Journal of Tropical Medicine. Research showed that a mixture of honey, beeswax and olive oil helped treat psoriasis, eczema, and dandruff.īeeswax: A minireview of its antimicrobial activity and its application in medicine. Helps ease certain dermatologic conditions: Beeswax can also be helpful in easing some dermatologic conditions.The traces of vitamin A in beeswax make it ideal for moisturizing hair. Locks in moisture: The formula and texture of beeswax make it a great choice for sealing split ends. ![]() However, this wasn't a placebo effect study, and there's no sign that beeswax was the sole reason for the growth. Purported to help with hair growth: While science is still waiting to confirm, a 2016 study found that a hair wax that contained beeswax significantly increased hair length over 30 days.Since it is not water soluble, beeswax prevents high humidity from causing your hair to frizz. Barrier against frizz: Due to its texture, is great for keeping hair straight.When mixed with a carrier oil or butter, beeswax is an excellent styling product, helping to keep your style in place, especially for short hair. Creates long-wearing hairstyles: One of the main uses for beeswax in hair is when starting dreadlocks or locs, as it is essential for getting the hair to lock and stay in place.It works best near the ends of the hair, as applying it too close to your scalp could make your hair look greasy. Smooths strands: The texture of beeswax makes it a great product for smoothing flyaways and frizz. ![]() |
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